![](http://i1343.photobucket.com/albums/o783/BLID_32377/27078b18-d551-493c-8088-98abc3ce71d5_zps1xphxpjm.png)
Don't know the anime or character.
I understand this thread is unusual for even Off-topic, so once I find out I'll lock this if possible.
If you want a more complete and contextual version of this picture look to I Hate Everything's "I Hate Anime Pt. 1" video, time stamp 6:23.
https://www.youtube.com/watch?v=u2-s49bBbtU