I'd bitch about how fires work even with no oxygen.
Pandora's atmosphere is a mixture of nitrogen, oxygen, carbon dioxide (>18%), xenon (>5.5%), methane, and hydrogen sulfide (>1%) and is about 20% denser than the atmosphere on Earth primarily due to the high percentage of Xenon; a heavy, colorless, odorless, and generally unreactive noble gas. The high concentration of carbon dioxide in the Pandoran atmosphere makes it extremely poisonous to humans, rendering them unconscious in 20 seconds and causing death in about 4 minutes. The hydrogen sulfide present is also quite poisonous; concentrations over 1000 ppm (0.1 %) can cause immediate collapse with subsequent loss of breathing, even after inhalation of a single breath.
tl;dr there's oxygen its the other stuff that kills the dudes without the mask things