To me it's like the start of a cross country race. When I do, I feel like a stalker and that I shouldn't, but it turns out stupid in the end. This is only when I add attractive females, though. A guy that is a new buddy that you met, its no problem. I dunno why, but it's like the most akward thing to do, and you want your profile to look good.
Post your process of adding someone as a friend.