Also, where is a good place to start with Frank Zappa. I'm interested and he has a stuff ton of material
This is my field of expertise.
If you like Jazz Fusion, go with Hot Rats. This is one of his best albums, only beaten by We're Only In It for the Money.
If you like his more comedy-rock style albums, start with Sheik Yerbouti or Joe's Garage.
There's also some killer instrumentals on Waka/Jawaka, Apostrophe (my personal favorite), and Shut Up and Play Your Guitar.
If you want to check out some of his best guitar solos, look up:
-Apostrophe
-Watermelon in Easter Hay
-Black Napkins (this solo is crazy good)
-Pink Napkins
-Heavy Duty Judy
-Five Five Five
-Outside Now
-Treacherous Cretins