Burlington is a very liberal city (not as liberal as the Bay Area, think a bit more centrist). It has a pretty nice downtown area, tons of outdoor activities to partake in -- as you're steps away from the mountains, and yards away from Lake Champlain. Burlington is very close to Montreal, and only a drive away from Boston and Portland (Maine, not Oregon). Oh it's also where Presidential candidate Sanders comes from.
All in all, it is a great little city with a lot to do and it's neat how you're moving there. Enjoy!
SOURCE: I've been all over VT on numerous occasions